Chelsea is back in the Champions League, after a 2-year absence, by winning last season's UEFA Conference League and FIFA Club World Cup.
FC Bayern have won four of their last five encounters with Chelsea across competitions.
Chelsea have only lost more Champions League matches against Barcelona (four) than against the German record champions (three).
Chelsea go into the game on the back of a bad result, as they conceded late to drop two points against Brentford at the weekend.
On the other hand, Bayern Munich have been perfect so far this season and won 5-0 at the weekend against Hamburger SV.
UEFA have announced the referee for the fixture. José María Sánchez from Spain will be the man with the whistle when Chelsea takes on Bayern Munich this week.
Sanchez has never refereed a game involved Chelsea before this. But it is worth mentioning that no senior English team has lost with him as the referee. That record stands at 8 wins and 3 draws from 11 games.
Bayern holds a strong record against English teams at home, winning eight of their last ten matches against them (D1 L1).
Manuel Neuer holds the record for the most Champions League clean sheets (60), surpassing Iker Casillas.
Harry Kane became the English player with the most total goals in Champions League history with 39 goals in 55 appearances for Tottenham and Bayern.
Kane has scored 19 goals in 25 Champions League appearances for Bayern.
He recently achieved the milestone of becoming the second English player to reach 50 Champions League goal contributions (goals and assists).
Nicolas Jackson, who joined Bayern Munich on loan from Chelsea this summer, is eligible to face his parent club under UEFA rules.
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